Course: Electrochemistry

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Course title Electrochemistry
Course code KEP/ECH
Organizational form of instruction Lecture + Tutorial
Level of course Bachelor
Year of study not specified
Semester Summer
Number of ECTS credits 2
Language of instruction Czech
Status of course Compulsory
Form of instruction Face-to-face
Work placements This is not an internship
Recommended optional programme components None
Lecturer(s)
  • Štekl Pavel, Ing. Ph.D.
  • Stachová Lenka, Ing. Ph.D.
Course content
Best subject characterization shows content of lectures and seminars, which are divided into theoretical parts and on laboratory parts. Lecture contents: 1.Atomic structure, quantum theory, valence band structure, atomic orbital, chemical bonds, styles of binding, interactions, ionic and covalent bond, physical properties of matters, periodic table, nomenclature. 2.Theory of acids and alkalis, neutralization reactions, electrolytes, salts, ionic compounds, dissociation, dissociation constants, pH explanation and computation. 3.Electrochemical potentials, oxidation reduction (redox) potential systems, redox formulas, enumeration of redox equations, electrode redox processes, electrode types, electrode reactions, electrode processes. Electrolysis, Faraday?s laws. 4.Primary and secondary electrochemical cells (batteries), principles and functions. Primary batteries based on manganese in acid and alkali media. Primary batteries based on lithium, special primary batteries based on mercury and other metals. Applications, variants, equations, and technical details. Technology comparisons. 5.Secondary batteries based on nickel, hydride and cadmium variants, equations, schemes, and technical details. Secondary batteries based on lead, process reversibility, schemes, and technical details. Charging and discharging characteristics, applications in automotive. Secondary batteries based on lithium, ionic and polymer variants, schemes, technical details, and operational conditions. 6.Fuel cells - introduction, fractionation, specifications, schemes, equations, technical details, and operational conditions. Types, advantage and disadvantages. 7.Hydrogen generation and storage. Photos and practical examples of laboratory and diploma thesis. Photovoltaic, photovoltaic principle, efficiency, applications, practical tests, and technical details. Photos from manufactory. Laboratory seminars contents: 1.Basics of chemistry such as notations, laws, formulas. Periodic table, valence band and its influence on reactions. Models of selected chemical substances. 2.Chemical equations, evaluation, and balancing. Neutralization, pH measuring, stoichiometry. 3.Balancing of common electrochemical processes, redox systems, methods of enumeration, examples. Solution conductivity measurement, galvanization, common examples of electrode processes, electrode surface optical analysis. 4.Primary and secondary batteries ? equations, reaction and processes description and calculations. Measurement on lead battery model, analysis of electrode surface changes. 5.Physical and chemical processes in fuel cells ? redox and catalytic reactions and its descriptions. Sample experiments and application possibilities of PEM, DMFC, and AFC fuel cells. 6.Measurement of load characteristics of PEM fuel cell, DMFC and AFC dynamics parameters testing. Calculation of fuel cell efficiency. Water hydrolysis. 7.Photovoltaic cell efficiency measurements. Inclusion test, evaluation, index inclusion.

Learning activities and teaching methods
Lecture with practical applications, E-learning, Cooperative instruction, One-to-One tutorial, Laboratory work
  • Contact hours - 26 hours per semester
  • Practical training (number of hours) - 13 hours per semester
  • Preparation for comprehensive test (10-40) - 15 hours per semester
  • Preparation for laboratory testing; outcome analysis (1-8) - 7 hours per semester
prerequisite
Knowledge
The precondition is an interest in chemistry and its use in electrical engineering and knowledge of biological sciences at least on high school level.
learning outcomes
Student is able to express in formulas and equations all important electrochemical actions, which form the bases of studied primary and secondary electrochemical sources and fuel cells. Have the knowledge to express the formulas of important acids, alkalis and other relevant chemical matter including its reactions and energetic balance. Student ia able to evaluate the significance, reactivity and other physical properties of selected materials using the theoretical background study of electrochemical potentials and reduction. Student knows how to express the nature of physical and chemical affinities of compounds even on level of electron configurations. In practical exercises, the students is able to verify the elementary operational and power facets of the fuel cell operation, furthermore they will try out the processes of neutralization, galvanization, conductometry and the transport of ion fragments in electrolyte. To pass this course, the student will prove his/her acquired knowledge of the subject in final test which will contain a complex sum of information included in the course. Great attention will be paid to the utility and practical applicability of obtained knowledge and experiences.
teaching methods
Laboratory work
E-learning
Cooperative instruction
One-to-One tutorial
Interactive lecture
assessment methods
Written exam
Test
Individual presentation at a seminar
Recommended literature
  • Doležel, Ivo. Elektrochemie. Plzeň : ZČU, 1998. ISBN 80-7082-410-7.


Study plans that include the course
Faculty Study plan (Version) Category of Branch/Specialization Recommended year of study Recommended semester
Faculty: Faculty of Electrical Engineering Study plan (Version): Commercial Electrical Engineering (16) Category: Electrical engineering, telecommunication and IT 3 Recommended year of study:3, Recommended semester: Summer